On the Structure of Kitol : (Ⅱ) Oppenauer Oxidation Product of Kitol
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- Yano Tomoki
- Laboratory of Fishery Chemistry, Faculty of Agriculture, Kyushu University
Bibliographic Information
- Other Title
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- キトールの構造に関する研究 : (Ⅱ)キトールのOppenauer酸化物
- キトールの構造に関する研究-2-キトールのOppenauer酸化物
- キトール ノ コウゾウ ニカンスルケンキュウ 2 キトール ノ Oppenau
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Abstract
One of two alcohol groups of kitol was oxidized by Oppenauer oxidation. A study of a carbonyl group of this oxidized kitol (F-Ⅰ) has been made by NMR spectrum (Fig.11). It was found that the carbonyl group is ketonic one indicating the presence of secondary alcohol group in kitol. The IR and NMR spectra of the oxidized kitol suggest that this ketone group is located in a five-membered ring, and that there exists an active methylene adjacent to the ketone group (Fig.11). It was also demonstrated that the oxidized kitol is almost quantitatively reduced to kitol with LiAlH_4.
Journal
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- 九州大學農學部學藝雜誌
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九州大學農學部學藝雜誌 31 (2/3), 49-56, 1976-12
Faculty of Agriculture, Kyushu University
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Keywords
Details 詳細情報について
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- CRID
- 1390853649767917312
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- NII Article ID
- 110001790389
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- NII Book ID
- AN0005519X
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- ISSN
- 03686264
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- DOI
- 10.15017/23223
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- HANDLE
- 2324/23223
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- NDL BIB ID
- 1799998
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- Text Lang
- ja
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- Data Source
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- JaLC
- IRDB
- NDL
- CiNii Articles