Analogy of van't Hoff Relationship for Thermally-Accessible Lattice Strain of Copper(II) Complex

DOI Web Site 13 References

Bibliographic Information

Other Title
  • Analogy of van't Hoff relationship for thermally-accessible lattice strain of copper(2) complex

Search this article

Description

In analogy with the mathematical form of thermodynamic van't Hoff equation (lnK = －ΔH/RT +ΔS/R) for equilibrium systems, we proposed a similar relationship for thermally-accessible lattice strain of a certain copper(II) complex exhibiting anisotropic distortion. For this purpose we assumed that the degree of lattice strain plays a similar role to the equilibrium constant in the van't Hoff equation. We tested some predominant peaks of XRD patterns in the temperature range of 100 - 300 K. We found that the temperature dependence of the degree of the lattice strain was consistent with our assumption. Deviation from reasonable results was attributed to the treatment of isotropic d-values and characteristics requested by the crystal symmetry.

Journal

  • Netsu Sokutei

    Netsu Sokutei 36 (5), 244-246, 2009-11-30

    The Japan Society of Calorimetry and Thermal Analysis

References(13)*help

See more

Keywords

Details 詳細情報について

Report a problem

Back to top