Effects of α-Tocopherol, β-Carotene and Epigallocatechin Gallate on the Oxidative Stability of Sunflower Oil

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  • Liu Chang
    College of Food Engineering, Harbin University of Commerce
  • Wang Weining
    College of Food Engineering, Harbin University of Commerce
  • Zhang Hairong
    School of Computer and Information Engineering, Harbin University of Commerce
  • Luo Shunian
    College of Food Engineering, Harbin University of Commerce Jiusan Food Co., LTD
  • Wang Xue
    College of Food Engineering, Harbin University of Commerce Jiusan Food Co., LTD
  • Wang Liqi
    College of Food Engineering, Harbin University of Commerce School of Computer and Information Engineering, Harbin University of Commerce
  • Yu Dianyu
    School of Food Science, Northeast Agricultural University

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<p>Using sunflower oil as the oil matrix, the antioxidant effects and types of interactions of three natural components, α-tocopherol, β-carotene and epigallocatechin gallate (EGCG), were investigated and the kinetic model of oxidation reaction was established. The results showed that the ability of the three antioxidants to scavenge DPPH radicals was ranked as EGCG > β-carotene > α-tocopherol in the concentration range of 0~100 mg/kg. 15 samples were obtained by combining two of three natural components. When the concentration ratios of β-carotene and EGCG were 1:20 and 1:7.5, α-tocopherol and EGCG were 1:13.3, 1:6, and 1:2, and α-tocopherol and β-carotene were 1:0.2 and 1:0.05, the type of interaction was synergistic, while the rest of the samples showed antagonistic effects. The sample with a 1:13.3 concentration of α-tocopherol and EGCG showed the longest induction period, the lowest oxidation rate constant, the highest activation energy, the best oxidative stability, and the longest shelf life at different temperatures. This compounded natural antioxidant was the most favorable for the stability of sunflower oil. This provides some theoretical basis for the development and application of compounded natural antioxidants in vegetable oils.</p>

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