O-25　ギ酸を利用したBaeyer–Villiger 酸化によるレブリン酸からのコハク酸生成

DOI

書誌事項

タイトル別名
  • O-25　Investigation of the reactivity of levulinic acid–succinic acid Baeyer–Villiger Oxidation with formic acid

抄録

<p>Levulinic acid is one of the platform chemicals synthesized from cellulose with the generation of formic acid. Succinic acid, which can be synthesized from levulinic acid by Baeyer–Villiger oxidation, is also one of the platform chemicals. Succinic acid is a versatile substance with a wide range of applications. In this study, we investigated the reactivity of levulinic acid-succinic acid reaction with performic acid, obtained from formic acid and H2O2. The yield of succinic acid was 3.76% after 180 min at 90 °C. Most of the formic acid and H2O2 were decomposed immediately after the start of the reaction, and the yields of the various products converged accordingly. This result suggested the concentrations of formic acid and H2O2 have a significant effect on succinic acid synthesis.</p>

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詳細情報 詳細情報について

  • CRID
    1390861471537474688
  • DOI
    10.20550/jiebiomassronbun.19.0_53
  • ISSN
    24238341
    24238333
  • 本文言語コード
    ja
  • データソース種別
    • JaLC
  • 抄録ライセンスフラグ
    使用不可

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