Transition-Metal Catalyzed Unimolecular Fragment Couplings
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- Tobisu Mamoru
- Graduate School of Engineering, Osaka University
Bibliographic Information
- Other Title
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- 遷移金属触媒を用いたフラグメントカップリング反応の開発
Abstract
<p>As alternative strategy to transition metal-catalyzed cross-coupling, unimolecular fragment coupling (UFC) is defined as the reaction format, in which the atom(s) in the middle of the molecule is extruded, and the remaining fragments are coupled. UFC is a potentially powerful strategy, as the starting materials are readily available through well-established methods, and the key bond formation event proceeds in an intramolecular manner, thereby allowing for high chemo- and stereoselectivity. Herein, we overview UFC reactions of ketones, esters, amides and acylsilanes with the elimination of carbon monoxide, carbon dioxide, isocyanate and oxygen atom.</p>
Journal
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- Journal of Synthetic Organic Chemistry, Japan
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Journal of Synthetic Organic Chemistry, Japan 82 (5), 450-460, 2024-05-01
The Society of Synthetic Organic Chemistry, Japan
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Keywords
Details 詳細情報について
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- CRID
- 1390863019774278400
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- ISSN
- 18836526
- 00379980
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- Text Lang
- ja
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- Data Source
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- JaLC
- Crossref
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- Abstract License Flag
- Disallowed