遷移金属触媒を用いたフラグメントカップリング反応の開発

DOI

書誌事項

タイトル別名
  • Transition-Metal Catalyzed Unimolecular Fragment Couplings

抄録

<p>As alternative strategy to transition metal-catalyzed cross-coupling, unimolecular fragment coupling (UFC) is defined as the reaction format, in which the atom(s) in the middle of the molecule is extruded, and the remaining fragments are coupled. UFC is a potentially powerful strategy, as the starting materials are readily available through well-established methods, and the key bond formation event proceeds in an intramolecular manner, thereby allowing for high chemo- and stereoselectivity. Herein, we overview UFC reactions of ketones, esters, amides and acylsilanes with the elimination of carbon monoxide, carbon dioxide, isocyanate and oxygen atom.</p>

収録刊行物

キーワード

詳細情報 詳細情報について

  • CRID
    1390863019774278400
  • DOI
    10.5059/yukigoseikyokaishi.82.450
  • ISSN
    18836526
    00379980
  • 本文言語コード
    ja
  • データソース種別
    • JaLC
  • 抄録ライセンスフラグ
    使用不可

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