パーフルオロブチル基とシクロヘキシル基を有するポリメタクリル酸エステル共重合体の表面特性

DOI 機関リポジトリ (HANDLE)

書誌事項

タイトル別名
  • SURFACE PROPERTY OF POLYMETHACRYLATE COPOLYMERS BEARING WITH PERFLUORBUTYL AND CYCLOHEXYL GROUPS

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説明

A variety of copolymers comprised of poly[2-(perfluorobutyl)ethyl methacrylate] (PC_4F_9MA) and poly(cyclohexyl methacrylate) (PCHMA) was synthesized and applied for the surface characterization by an X-ray photoelectron spectroscopy and the contact angle measurements with water and n-dodecane droplets. As expected, these fluorine-containing copolymers always showed the hydrophobic property due to the concentration of C_4F_9 groups at the top of the film surface. Interestingly, the microphase separation of PC_4F_9MA segments at the film surface leads the block copolymer surface structure to the same as the PC_4F_9MA homopolymer. In addition, the random copolymer film showed excellent water/oil repellency, in which the pining effects of C_4F_9 groups reduced.

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キーワード

詳細情報 詳細情報について

  • CRID
    1390863937794536832
  • DOI
    10.15002/00030645
  • HANDLE
    10114/00030645
  • ISSN
    24368083
  • 本文言語コード
    ja
  • 資料種別
    departmental bulletin paper
  • データソース種別
    • JaLC
    • IRDB
  • 抄録ライセンスフラグ
    使用可

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