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Graphene Synthesis on Silver Foil by Chemical Vapor Deposition Using Ethanol
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- Iwatani Hikaru
- Department of Information Electronics, Faculty of Engineering, Fukuoka Institute of Technology
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- Maeda Fumihiko
- Department of Information Electronics, Faculty of Engineering, Fukuoka Institute of Technology
Description
<p>We investigated the growth of graphene on silver surfaces by chemical vapor deposition (CVD) with ethanol as the gas material under various growth conditions. The investigation was based on Raman spectroscopy analysis. We determined that over 900°C is required to decompose the ethanol. Additionally, we proposed a graphene growth mechanism on the silver surfaces. Herein, the formation of the graphene nuclei and silver evaporation are competing processes, which limits the crystallinity of the graphene. Furthermore, we demonstrated that the addition of hydrogen during the CVD growth and the modifications of the conditions of the sample cooling process after the growth are valid for expanding the growth conditions and improving the crystallinity of graphene. The modifications included a low cooling rate of the substrates, maintenance of the environmental pressure equal to that of the growth, and a continuous supply of ethanol after the growth. The results indicate that the suppression of silver atom evaporation is the key to obtaining high-crystallinity graphene.</p>
Journal
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- e-Journal of Surface Science and Nanotechnology
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e-Journal of Surface Science and Nanotechnology 23 (2), 174-181, 2025-05-17
The Japan Society of Vacuum and Surface Science
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Keywords
Details 詳細情報について
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- CRID
- 1390867344224283904
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- ISSN
- 13480391
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- Text Lang
- en
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- Data Source
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- JaLC
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- Abstract License Flag
- Allowed