Cu–20 at.% Ni–6.7 at.% Al合金の時効にともなう組織と硬さの変化

  • 榛木 隆太
    大阪府立大学 工学研究科 マテリアル工学分野
  • 千星 聡
    東北大学 金属材料研究所
  • 金野 泰幸
    大阪府立大学 工学研究科 マテリアル工学分野
  • 高杉 隆幸
    大阪府立大学 工学研究科 マテリアル工学分野
  • 首藤 俊也
    DOWAメタルテック株式会社 金属加工事業部 磐田技術センター
  • 兵藤 宏
    DOWAメタルテック株式会社 金属加工事業部 磐田技術センター

書誌事項

タイトル別名
  • Microstructure and Hardness of Isothermally Aged Cu–20 at.% Ni–6.7 at.% Al Alloy
  • Cu-20 at.% Ni-6.7 at.% AI合金の時効にともなう組織と硬さの変化
  • Cu-20 at.% Ni-6.7 at.% AI ゴウキン ノ ジコウ ニ トモナウ ソシキ ト カタサ ノ ヘンカ

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説明

<p>The microstructural evolution and strengthening of Cu–20 at.% Ni–6.7 at.% Al alloy during isothermally aging at 450 to 650℃ were investigated to understand age–induced precipitation and hardening behavior for Cu–Ni–Al system. In an initial stage of aging, fine ordered Ni3Al particles with a size of several tens nm was coherently formed in parent grains of Cu solid solution in a continuous precipitation manner, together with cellular components composed of Cu solid solution and fine fibrous Ni3Al phases by grain boundary reaction. During furthermore aging, fine Ni3Al particles in grains were continuously nucleated and grown, while cellular components at grain boundaries seemed not to be developed. The alloy exhibited a maximum hardness more than 320 Hv by aging at 550 to 650℃, which was greatest among conventional copper alloys. The hardening in the alloy was principally contributed to a high–density dispersion of fine ordered Ni3Al particles in grains. According to the time–temperature transformation (TTT) diagram for the alloy, aging at 600 to 650℃ should be effective to obtain a microstructure with fine dispersion of ordered Ni3Al particles and without cellular components, resulting in an excellent strength with the alloy.</p>

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