Effect of Electrolyte Additive on the Electrochemical Stability of Aluminum-graphite Battery (Supporting Information)

メタデータ

公開日
2023-05-15
利用開始日 (公開予定日)
2023-05-15
最終更新日
2023-05-30
資源種別
Dataset
サイズ
  • 489.08KB
バージョン
1.0
権利情報
  • CC BY-NC-SA 4.0
DOI
  • 10.50892/data.electrochemistry.22729091.v1
  • 10.50892/data.electrochemistry.22729091
公開者
The Electrochemical Society of Japan
データ作成者 (e-Rad)
  • LI Fengcui
  • LIU Chengyuan
  • LIU Rujia
  • YU Jiangyu
  • LIU Zhiwei

説明

<p>The effect of electrolyte additive 1,2-dichloroethane (DCE) on the electrochemical stability of aluminum-graphite battery using acetamide-AlCl3 electrolyte is investigated comparatively. Original dendritic and dead aluminum are observed in Al-Al cells at a high operation rate. Original dendritic and dead aluminum are observed in the anode and separator of Al-Al cells at a high operation rate. DCE is a preferred electrolyte additive to reduce the polarization of the acetamide-AlCl3 electrolyte. Furthermore, DCE can effectively suppress the dendrites on the Al anode in Al|acetamide-AlCl3|Al cells. Besides, it has a positive effect on improving the discharge specific capacity and cycle stability of aluminum-graphite batteries with a high coulombic efficiency over 300 cycles. This result indicates that organic additive is suitable to improve the electrochemical performance of aluminum-graphite batteries.</p>

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