Synthesis and Crystal Structure of a [70]Fullerene–Pentacene Monoadduct

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<jats:title>Abstract</jats:title> <jats:p>We succeeded in the first isolation of a single pure regioisomer of a C70–acene monoadduct. 1,9-Diels–Alder monoadducts of C70 with pentacene derivatives were obtained by not only the Diels–Alder reaction but also a one-pot reaction using stable dihydropentacene derivatives, 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ), and C70. The X-ray crystallographic study of a single pure regioisomer 2b confirmed positions of the linkage between C70 and acenes for the first time, and revealed unique columnar stacks.</jats:p>

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