Synthesis and Characterization of a Di-µ-oxalato Tetracopper(Ⅱ) Complex with Tetranucleating Macrocyclic Ligand
この論文をさがす
抄録
<jats:title>Abstract</jats:title> <jats:p>A tetracopper(II) complex containing two oxalate anions in the metal-based host cavity, [Cu4(Lpy)(µ-ox)2](PF6)2·2(2-PrOH), where ox2−: oxalato (C2O42−), was prepared by reacting H2Lpy, a phenol-based tetranucleating macrocyclic ligand with four pyridylmethyl pendant arms, Cu(ClO4)2·6H2O, and sodium oxalate (1:4:2 stoichiometry, respectively) in methanol, followed by exchange of the counteranion with excess of NH4PF6. Single-crystal X-ray diffraction of 1 revealed that two {Cu(II)Cu(II)} units, bridged by a phenolato group of Lpy2−, were connected by two oxalato anions, to construct a rectangular “{CuCu}(µ-ox)2{CuCu}” tetranuclear framework. This rectangular framework was maintained in DMF solution. The magnetic measurement of 1 in the 2–300 K range revealed antiferromagnetic behavior. The antiferromagnetic interaction in this complex occurs between the Cu(II) centers bridged by an oxalate (J = −140 cm−1).</jats:p>
収録刊行物
-
- Bulletin of the Chemical Society of Japan
-
Bulletin of the Chemical Society of Japan 89 (4), 430-436, 2016-04
Tokyo : Chemical Society of Japan
- Tweet
キーワード
詳細情報 詳細情報について
-
- CRID
- 1520291854898881152
-
- NII論文ID
- 130005144948
-
- NII書誌ID
- AA00580132
-
- ISSN
- 00092673
- 13480634
-
- NDL書誌ID
- 027243248
-
- 本文言語コード
- en
-
- NDL 雑誌分類
-
- ZP1(科学技術--化学・化学工業)
-
- データソース種別
-
- NDL
- Crossref
- CiNii Articles