Selected Papers : Identification of Hydrogen-Bonded Oligomers in Associating Liquid by HNMR : 1-Phenyl-1-cyclohexanol
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Abstract
<jats:title>Abstract</jats:title> <jats:p>Nonmonotonous temperature dependence, which suggests formation of closed oligomer(s) via hydrogen-bonds, is detected in heat capacity and dielectric constant of the title compound in the liquid state. The 1H NMR signal of hydroxy protons showed a temperature-dependent fine structure. Quantum-chemical calculations on oligomers of several types revealed that the fine structure is plausibly interpreted as a temperature-dependent formation/destruction of oligomers. A coherent analysis of calorimetric, FT-IR, dielectric, and 1H NMR results shows that the neat liquid of the title compound consists mostly of closed (square) tetramers via H-bonds at lower temperatures, and oligomers with open (or straight) H-bonding and non-H-bonding (monomer) at higher temperature.</jats:p>
Journal
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- Bulletin of the Chemical Society of Japan
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Bulletin of the Chemical Society of Japan 86 (5), 569-576, 2013-05
Tokyo : Chemical Society of Japan
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Details 詳細情報について
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- CRID
- 1521417754795270656
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- NII Article ID
- 10031167848
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- NII Book ID
- AA00580132
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- ISSN
- 00092673
- 13480634
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- NDL BIB ID
- 024473632
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- Text Lang
- en
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- NDL Source Classification
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- ZP1(科学技術--化学・化学工業)
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- Data Source
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- NDL
- Crossref
- CiNii Articles
- KAKEN