An attempt to convert glycine residues to threonine residues in polyglycine

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Abstract

<jats:title>Abstract</jats:title> <jats:p>When polyglycine was reacted with acetaldehyde in liquid ammonia in the presence of metallic sodium, it was observed that 7∼9% of the threonine residues were formed from glycine residues. From the hydrolyzate of the modified polyglycine, threonine could be isolated by the aid of the O→N acetyl shift reaction. It was shown that the threonine thus isolated was 35.6% allothreonine.</jats:p>

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