Reduction of organic compounds with Urushibara catalysts under high pressure,pt.9

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  • Reduction of organic compounds with Urushibara catalysts under high pressure , pt.9

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<jats:title>Abstract</jats:title> <jats:p>The catalytic reduction of deoxybenzoin, benzoin, benzil and furil with various Urushibara catalysts under high pressure were studied. It was found that benzil and furil was converted into the corresponding α-ketols by the partial reduction under proper condition.</jats:p> <jats:p>Some modifications for the preparation of the Urushibara catalyst were attained. The newly developed precipitated nickel prepared by a very simple way proved to give a catalyst as active as the usual Urushibara nickel catalyst for practical use. Hydrochloric acid was found to be applicable for the digestion of the precipitated nickel in place of acetic acid.</jats:p>

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