Computational Picture of Silyl Transfer from Silylsilatranes to Arylpalladium Chloride
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<jats:title>Abstract</jats:title> <jats:p>The previously reported palladium-catalyzed silylation of aryl chlorides with silylsilatranes was theoretically reinvestigated by DFT calculations with a focus on the effect of the transannular Si–N coordination on silyl transfer. The Si–N coordination proved to be not so influential as to accelerate the silyl transfer. However, it should be of benefit to use silylsilatranes as silylating agents because of their easy handling and facile preparation.</jats:p>
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- Bulletin of the Chemical Society of Japan
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Bulletin of the Chemical Society of Japan 89 (2), 192-194, 2016-02
Tokyo : Chemical Society of Japan
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詳細情報 詳細情報について
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- CRID
- 1521699229656978688
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- NII論文ID
- 130005125597
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- NII書誌ID
- AA00580132
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- ISSN
- 00092673
- 13480634
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- NDL書誌ID
- 027102644
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- 本文言語コード
- en
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- NDL 雑誌分類
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- ZP1(科学技術--化学・化学工業)
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- データソース種別
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- NDL
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