Anomalous Electrochemical Behavior of 1,4-Benzoquinone upon the Addition of Silver Ion
Bibliographic Information
- Other Title
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- Anomalous Electrochemical Behavior of 1 4 Benzoquinone upon the Addition of Silver Ion
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Abstract
<jats:title>Abstract</jats:title> <jats:p>A cyclic voltammogram of 1,4-benzoquinone showed a couple of redox waves in aqueous solution. Upon adding a trace amount of silver ion, the cyclic voltammogram exhibited an anomalous behavior: a shift of the reduction peak toward a negative potential and the appearance of a new re-oxidation peak at a much more positive potential. This anomalous electrochemical behavior was investigated in terms of both interactions in bulk and on the electrode surface using some kinds of metal-ion additives and some working-electrode materials. It is suggested that the underpotential deposition of silver ion is primarily responsible for the anomalous electrochemical behavior of 1,4-benzoquinone. This was demonstrated by a measurement of cyclic voltammograms using a silver-deposited electrode at an underpotential.</jats:p>
Journal
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- Bulletin of the Chemical Society of Japan
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Bulletin of the Chemical Society of Japan 73 (12), 2753-2757, 2000
Tokyo : Chemical Society of Japan
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Keywords
Details 詳細情報について
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- CRID
- 1521980705151049472
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- NII Article ID
- 10009156642
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- NII Book ID
- AA00580132
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- ISSN
- 00092673
- 13480634
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- NDL BIB ID
- 5597312
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- Text Lang
- en
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- NDL Source Classification
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- ZP1(科学技術--化学・化学工業)
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- Data Source
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- NDL
- Crossref
- CiNii Articles