Correlation Diagrams of Epimeric Stereoisograms for Stereoisomerism of Cyclopropane Derivatives
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<jats:title>Abstract</jats:title> <jats:p>Stereoisomerism of cyclopropanes is systematically discussed by means of stereoisograms and their correlation diagrams. A cyclopropane skeleton is governed by a main RS-stereoisomeric group constructed from its point group D3h, where the main RS-stereoisomeric group generates a set of main stereoisograms. An epimerization process at each of the carbon centers in the cyclopropane skeleton is characterized by an epimeric RS-stereoisomeric group, which generates a set of epimeric stereoisograms. The main RS-stereoisomeric group is combined with the epimeric RS-stereoisomeric groups, generating a stereoisomeric group for characterizing the cyclopropane skeleton. A set of epimeric stereoisograms at each RS-stereogenic center along with a set of main stereoisograms constructs a correlation diagram of stereoisograms. Such correlation diagrams are used to discuss local chirality and local RS-stereogenicity, where the RS-stereogenicity is correlated to the capability of giving RS-stereodescriptors.</jats:p>
収録刊行物
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- Bulletin of the Chemical Society of Japan
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Bulletin of the Chemical Society of Japan 91 (8), 1226-1240, 2018-08
Tokyo : Chemical Society of Japan
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詳細情報 詳細情報について
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- CRID
- 1521980705602733440
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- NII論文ID
- 130007434623
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- NII書誌ID
- AA00580132
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- ISSN
- 00092673
- 13480634
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- NDL書誌ID
- 029141021
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- 本文言語コード
- en
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- NDL 雑誌分類
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- ZP1(科学技術--化学・化学工業)
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- データソース種別
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- NDL
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