Cooperation of Hydrogen-Bond and Charge-Transfer Interactions in Molecular Complexes in the Solid State

DOI PDF Web Site 被引用文献23件 参考文献269件

この論文をさがす

抄録

<jats:title>Abstract</jats:title> <jats:p>Our recent studies for the development of conducting charge-transfer complexes with well-defined assembled structures based on the cooperation of hydrogen-bond and charge-transfer interactions are described. We have designed and synthesized hydrogen-bonded charge-transfer complexes based on (1) tetrathiafulvalene derivatives having nucleobases, aminobenzo and imidazole moieties, and (2) tetracyanoquinodimethane radical anion salts with hydrogen-bond-functionalized phenalenyl and protonated oligo(imidazole) cations. The directional and site-selective hydrogen-bonds formed various supramolecular network structures, constructing segregated columns as the conduction path. Furthermore, the high polarity of hydrogen-bonds caused strong donor–acceptor or cation–anion electrostatic interactions modulating the ionicity of component molecules and the electronic structure of conduction columns. Such electronic modulation effects in addition to controlling the molecular arrangement realized the first purely organic molecular metal based on a hydrogen-bonded charge-transfer complex in the p-chloranil complex of an imidazole-functionalized tetrathiafulvalene derivative. The proton-donating/accepting ability of the hydrogen-bonding sites afforded the simultaneous proton- and charge-transfer complexes, demonstrating an important prompt for the realization of cooperative proton–electron-transfer systems.</jats:p>

収録刊行物

被引用文献 (23)*注記

もっと見る

参考文献 (269)*注記

もっと見る

関連プロジェクト

もっと見る

キーワード

詳細情報 詳細情報について

問題の指摘

ページトップへ