A selective phosphorylation by means of α-bromocyanoacetamides and trialkyl phosphites

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  • A selective phosphorylation by means of アルファ-bromocyanoacetamides and trialkyl phosphites

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<jats:title>Abstract</jats:title> <jats:p>A method of selective phosphorylation by means of α-bromocyanoacetamides and trialkyl phosphites was devised. In this method, various phosphates, pyrophosphates and phosphoramidate were obtained in excellent yields under mild conditions without isolating the intermediate, enol-phosphate.</jats:p> <jats:p>The use of dibromocyanoacetamide in place of monobromocyanoacetamide produced the same results, the yields being, however, less.</jats:p> <jats:p>A new method for the preparation of monobromocyanoacetamide was also described.</jats:p>

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