Photoisomerization mechanism of all-Z-oligo(phenylenevinylene)s

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  • Photoisomerization mechanism of all Z oligo phenylenevinylene s

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<jats:title>Abstract</jats:title> <jats:p>Photoisomerization mechanism of para-substituted oligo(phenylenevinylene)s (OPVs) was dependent on the number of olefin units. While mono-olefin OPV1 underwent two-way photoisomerization, other OPVs (OPV2, OPV3, and OPV4) underwent photochemical one-way Z-to-E isomerization. As the number of olefin units increased, contribution of the triplet excited state to the Z-to-E isomerization becomes larger.</jats:p>

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