Magnesium-Promoted Reductive Silylation and Acylation of Tropone and Tropone Acetal

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<jats:title>Abstract</jats:title> <jats:p>Magnesium-promoted reductive coupling of chlorotrialkylsilanes and tropone or tropone acetal in DMF, followed by oxidation with 2,3-dichloro-5,6-dicyano-1,4-benzoquinone in benzene gives 2-trialkylsilyltropones as the main product, and the reductive coupling of tropone with acid anhydrides under similar reaction conditions yields benzene derivatives after ring contraction.</jats:p>

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