Unusual reaction course of styrenes to 2-arylethyltriphenylphosphonium salts
書誌事項
- タイトル別名
-
- Unusual reaction course of styrenes to 2 arylethyltriphenylphosphonium salts
この論文をさがす
抄録
<jats:title>Abstract</jats:title> <jats:p>1-Arylethyltriphenylphosphonium bromides thermally rearranged to 2-arylethyltriphenylphosphonium bromides. Direct formation of 2-arylethylphosphonium bromides was achieved by reacting styrene, HBr, and triphenylphosphine. On the other hand, thermolysis of 1-indanyltriphenylphosphonium bromide gave indene and triphenylphosphonium bromide. From deuterium and 13C-labeled experiments, the interconversion of primary and secondary cation intermediates was suggested. No neighboring phenyl group (phenonium cation intermediate) interaction was observed.</jats:p>
収録刊行物
-
- Bulletin of the Chemical Society of Japan
-
Bulletin of the Chemical Society of Japan 80 (9), 1785-1790, 2007
Tokyo : Chemical Society of Japan
- Tweet
キーワード
詳細情報 詳細情報について
-
- CRID
- 1523669554588641280
-
- NII論文ID
- 10019847346
-
- NII書誌ID
- AA00580132
-
- ISSN
- 00092673
- 13480634
-
- NDL書誌ID
- 8902755
-
- 本文言語コード
- en
-
- NDL 雑誌分類
-
- ZP1(科学技術--化学・化学工業)
-
- データソース種別
-
- NDL
- Crossref
- CiNii Articles