The Chemistry of Germanium-Containing Heavy Ketones
Bibliographic Information
- Other Title
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- Chemistry of Germanium-Containing Heavy Ketones
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Description
<jats:title>Abstract</jats:title> <jats:p>The recent applications of an extremely bulky and efficient steric protection group, 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl (denoted as Tbt in this article), to the kinetic stabilization of a series of doubly bonded compounds between germanium and heavier chalcogen atoms (we coin the expression “germanium-containing heavy ketones” for this family of heavier congeners of germanone) are described. Combination of a Tbt group with some other bulky aromatic or alkyl substituent enabled us to synthesize the novel germanium-containing double-bond species [Tbt(R)Ge=X; R = 2,4,6-triisopropylphenyl (Tip) or bis(trimethylsilyl)methyl (Dis)] such as germanethiones (X = S), germaneselones (X = Se), and germanetellones (X = Te) as stable crystalline compounds, while the germanone [Tbt(Tip)Ge=O], the most reactive species among the germanium-containing heavy ketones, was found to be very difficult to isolate and was evidenced only by the trapping reactions. The X-ray crystallographic analysis of the isolated germanium-containing heavy ketones revealed a completely trigonal planar geometry around their germachalcogenocarbonyl units and their ideally doubly bonded character, which was also confirmed by their spectroscopic data.</jats:p>
Journal
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- Bulletin of the Chemical Society of Japan
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Bulletin of the Chemical Society of Japan 72 (8), 1665-1684, 1999-08
Tokyo : Chemical Society of Japan
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Details 詳細情報について
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- CRID
- 1523951028242222080
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- NII Article ID
- 10009137177
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- NII Book ID
- AA00580132
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- ISSN
- 00092673
- 13480634
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- NDL BIB ID
- 4837091
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- Text Lang
- en
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- NDL Source Classification
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- ZP1(科学技術--化学・化学工業)
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- Data Source
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- NDL
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