Iridium-Catalyzed Reaction of 1-Naphthols, N-(1-Naphthyl) benzenesulfonamides, and Salicylaldehyde with Internal Alkynes
書誌事項
- タイトル別名
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- Iridium Catalyzed Reaction of 1 Naphthols N 1 Naphthyl benzenesulfonamides and Salicylaldehyde with Internal Alkynes
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<jats:title>Abstract</jats:title> <jats:p>1-Naphthols efficiently couple with internal alkynes via cleavage of the C–H bond at the peri-position in the presence of a catalyst system of [IrCl(cod)]2/PBut3 to selectively afford the corresponding 8-vinyl-1-naphthol derivatives. N-(1-Naphthyl)benzenesulfonamides can similarly react with the alkynes. The reaction of salicylaldehyde with the alkynes using the catalyst system gives 2-hydroxyphenyl vinyl ketones via cleavage of the aldehyde C–H bond.</jats:p>
収録刊行物
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- Bulletin of the Chemical Society of Japan
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Bulletin of the Chemical Society of Japan 74 (9), 1727-1735, 2001
Tokyo : Chemical Society of Japan
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詳細情報 詳細情報について
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- CRID
- 1523951030123967872
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- NII論文ID
- 10009165465
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- NII書誌ID
- AA00580132
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- ISSN
- 00092673
- 13480634
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- NDL書誌ID
- 5926927
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- 本文言語コード
- en
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- NDL 雑誌分類
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- ZP1(科学技術--化学・化学工業)
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- データソース種別
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- NDL
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