Posttreatment Technique for S[N]2 Alkylation of Aromatics with Alkyl Halides : Aiming toward Large-Scale Synthesis of Building Blocks for Soft π-Molecular Materials
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<jats:title>Abstract</jats:title> <jats:p>Unreacted alkyl halide and byproduct olefin contaminants in products of SN2 alkylation reactions of aromatic compounds can be efficiently removed by sequential posttreatments with a base and a boron compound (sodium borohydride or 9-borabicyclo[3.3.1]nonane), followed by column chromatography on silica gel. These treatments permit large-scale purification of various alkylated aromatics, thereby assisting in the development of soft π-conjugated materials, such as monomers for semiconducting polymers or alkylated π-functional liquids.</jats:p>
収録刊行物
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- Bulletin of the Chemical Society of Japan
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Bulletin of the Chemical Society of Japan 91 (8), 1258-1263, 2018-08
Tokyo : Chemical Society of Japan
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詳細情報 詳細情報について
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- CRID
- 1524232504718478720
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- NII論文ID
- 130007434142
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- NII書誌ID
- AA00580132
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- ISSN
- 00092673
- 13480634
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- NDL書誌ID
- 029141061
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- 本文言語コード
- en
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- NDL 雑誌分類
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- ZP1(科学技術--化学・化学工業)
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- データソース種別
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- NDL
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