SYNTHESIS OF DIBEKACIN (3',4'-DIDEOXYKANAMYCIN B) FROM D-GLUCOSAMINE AND D-GLUCOSE(Communication to the Editor)

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An aminoglycoside antibiotic, dibekacin (=3',4'-dideoxykanamycin B) (22), has been synthesized from D-glucosamine and D-glucose using an oxidative decarboxylation reaction with lead tetraacetate and a reductive deacetoxylation reaction with sodium borohydride as keyreactions.

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