The [4+2] Cycloaddition of 1,6-Dihydro-2-dimethylamino-4,6,6-trimethylpyrimidine with Acetylenic Compounds(Organic,Chemical)

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説明

1,6-Dihydro-2-dimethylamino-4,6,6-trimethylpyrimidine reacted with acetylenic compounds containing electron-withdrawing groups to yield 2-dimethylaminopyridine derivatives. When monosubstituted acetylenes were used, 4-unsubstituted pyridines were selectively obtained. The results of MINDO/3 calculations are consistent with this regioselectivity.

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詳細情報 詳細情報について

  • CRID
    1570572702348745600
  • NII論文ID
    110006281311
  • NII書誌ID
    AA00602100
  • ISSN
    00092363
  • 本文言語コード
    en
  • データソース種別
    • CiNii Articles

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