PREPARATION AND REACTION OF NOVEL OXYGEN ESTER ENOLATES, 1, : REACTION OF THIOGLYCOLATE WITH ALDEHYDES USING DIALKYLBORYL TRIFLATE

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Description

With the assistance of the electron withdrawing effect of divalent sulfur substituent, boron ester enolates were formed from the corresponding oxygen esters in the presence of dialkylboryl trifluoromethanesulfonate. These novel oxygen ester enolates reacted smoothly with aldehydes to produce the usual syn-aldol products.

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Details 詳細情報について

  • CRID
    1570572702505303168
  • NII Article ID
    110003654736
  • NII Book ID
    AA00602100
  • ISSN
    00092363
  • Text Lang
    en
  • Data Source
    • CiNii Articles

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