Effect of <I>p</I>H on the Gelation of Phenol-modified Melamine Resin and the Morphology of Gelled Resin
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- KOBAYASHI Yuji
- Ibaraki Research Laboratory, Hitachi Chemical Co., Ltd.
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- SAKATA Toichi
- Ibaraki Research Laboratory, Hitachi Chemical Co., Ltd.
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- MUKOYAMA Yoshiyuki
- Goi Work, Hitachi Chemical Co., Ltd.
Bibliographic Information
- Other Title
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- フェノール変性メラミン樹脂の硬化及びゲル化物のモルホロジーに及ぼす<I>p</I>Hの影響
Description
Effect of pH on the gelation of phenol-modified melamine resin was investigated, focusing on the rate of gelation, the morphology of gelled resin, and the flexural strength of cured resin. It is confirmed that pH of varnishes influences the rate of gelation and also the temperature dependence of flexural strength. It is found that gelled resins have different sea-and-island structures depending on the pH of varnishes. The resins gelled under acid conditions have a melamine sea structure while the ones under alkaline conditions have phenol sea structure.
Journal
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- Journal of Network Polymer,Japan
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Journal of Network Polymer,Japan 11 (2), 67-78, 1990
Japan Thermosetting Plastics Industry Association
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Details 詳細情報について
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- CRID
- 1570572703151023360
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- NII Article ID
- 130003388770
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- ISSN
- 03884384
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- Text Lang
- ja
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- Data Source
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- CiNii Articles