Synthesis of a Bicyclo[3.2.1]octane Analogue of Isocarbacyclin(Organic,Chemical)

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A new isocarbacyclin analogue (1a), containing a bicyclo[3.2.1]octane ring system, has been synthesized by means of a regioselective rearrangement of the cyclopropyl carbinol (8) to the homoallyl bromide (9) with hydrobromic acid. Compound la showed very weak inhibitory activity against platelet aggregation.

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