A NOTE ON THE A-RING CONFORMATION IN 2-CHLORO-1,2-DIHYDROSANTONINS

  • 太田 泰彦
    Department of Chemistry, Faculty of Science, Hokkaido University
  • ハイメ カルロス
    Department of Chemistry, Faculty of Science, Hokkaido University
  • 大沢 映二
    Department of Chemistry, Faculty of Science, Hokkaido University
  • 飯高 洋一
    Faculty of Pharmaceutical Sciences, University of Tokyo
  • 清水 信子
    Pharmaceutical Institute, School of Medicine, Keio University
  • 西原 祥子
    Pharmaceutical Institute, School of Medicine, Keio University
  • 大坂 哲司
    Pharmaceutical Institute, School of Medicine, Keio University
  • 堀 均
    Pharmaceutical Institute, School of Medicine, Keio University
  • 柴田 徹一
    Pharmaceutical Institute, School of Medicine, Keio University
  • 稲山 誠一
    Pharmaceutical Institute, School of Medicine, Keio University

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説明

The half-chair and half-boat conformations observed by X-ray analysis for the A-ring of 2α- and 2β-chloro-1,2-dihydro-1-α-santonin 1,respecitvely, should be regarded as a deformed sofa conformation based on molecular mechanics.

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