Aromatic Annelation with α-PhenyIsulfinyl-γ-butyrolactones. A Novel Route to 4-(2-Hydroxyalkyl)-1,3-benzenediols(Organic,Chemical)
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- OZAKI Y.
- Faculty of Pharmaceutical Sciences, Josai University
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- MOCHIDA KEIKO
- Faculty of Pharmaceutical Sciences, Josai University
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Description
A number of 4-(2-hydroxyalkyl)-1,3-benzenediols (4) were synthesized by thermolysis of 1,3-cyclohexadiones (3), which were obtained by the reaction of α-phenylsulfiyl-γ-butyrolaetones (1) with α,β-unsaturatcd ketones (2), providing a new aromatic annelation. One of the compounds thus obtained, 4-(3,4-dihydro-4-hydroxy-7-methoxy-2H-1-benzopyran-3-yl)-1,3-benzenediol (4n), was converted to isomedicarpin (5b) and hornopterocarpin (5c).
Journal
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- Chem.Pharm.Bull.
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Chem.Pharm.Bull. 35 1790-1795, 1987
The Pharmaceutical Society of Japan
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Keywords
Details 詳細情報について
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- CRID
- 1571417127279370368
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- NII Article ID
- 110006281127
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- NII Book ID
- AA00602100
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- ISSN
- 00092363
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- Text Lang
- en
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- Data Source
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- CiNii Articles