Studies on Monoterpene Glucosides and Related Natural Products. XLVII. Synthesis of ^3H-and ^2H-labeled Iridodial Derivatives for Studies on the Biosynthesis of Iridoid Glucosides

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説明

For studies on the biosynthesis of iridoid glucosides, four labeled compounds, i.e., [10-^3H]-iridotrial (4), [10-^3H]-7,8-dehydroiridodial (6), [10-^3H]-7,8-dehydroiridotrial (7) and [10-^2H_3]-iridodial (3), along with the known [10-^3H]-iridodial glucoside (10) and [10-^3H]-iridodial (3) were prepared from geniposide (11). Furthermore, [11-^2H_3]-7,8-dehydroiridodial (6) was derived from mussaenoside (14).

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