Studies on Organic Fluorine COmpounds. IL. The Ene Reaction of Trifluoroacetone

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書誌事項

公開日
1986
公開者
公益社団法人日本薬学会

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説明

The ene reaction of 1,1,1-trifluoroacetone with various olefinic compounds proceeded in the presence of aluminum chloride at low temperature to give allylmethyl (trifluoromethyl)carbinols. Olefinic compounds with a terminal vinyl group reacted smoothyl, but some olefins with an inner double bond did not react at all. Trifluoroacetone was also found to undergo a Friedel-Crafts type reaction with aromatic compounds.

収録刊行物

  • Chem. Pharm. Bull.

    Chem. Pharm. Bull. 34 1546-1552, 1986

    公益社団法人日本薬学会

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