Retentive solvolysis. Part 14. The methanol-perturbed phenolysis of optically active 2,2-dimethyl-1-(p-methoxyphenyl)propyl p-nitrobenzoate. The mechanism and the structure of the second ion-pair intermediate
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説明
<jats:title>Abstract</jats:title><jats:p>In contrast to the phenolysis of (I) in pure phenol, the title reaction affords partially inverted (IV), slightly inverted (VI) and (VII) and partially retained (V) with predominant racemization in both the presence and absence of added salt.</jats:p>
収録刊行物
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- Journal of the Chemical Society, Perkin Transactions 2
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Journal of the Chemical Society, Perkin Transactions 2 1875-, 1988-01-01
Royal Society of Chemistry (RSC)