?Living-like? cationic polymerization of isobutyl vinyl ether initiated by carboxyl groups of solid surface in the presence of zinc chloride

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We investigate the effects of Zn Cl 2 as catalyst on the cationic polymerization of isobutyl vinyl ether (IBVE) initiated by carboxyl groups introduced onto crosslinked polstyrene bead surface and those on poly(acrylic acid-co-divinylbenzene) cation exchange resin surface as model compounds of carbon black. In addition, the grafting reactions of poly(IBVE) with controlled molecular weight and narrow MWD onto polystyrene bead and cation exchange resin after the quenching of the polymerization with methanol were discussed

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