STEREOSELECTIVE SYNTHESIS OF OPTICALLY ACTIVE β-LACTAMS BY THE REACTION OF CHIRAL IMINES DERIVED FROM ERYTHRO-2-AMINO-1,2-DIPHENYLETHANOL WITH ESTER ENOLATES
書誌事項
- タイトル別名
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- ChemInform Abstract: Stereoselective Synthesis of Optically Active β‐Lactams by the Reaction of Chiral Imines Derived from erythro‐2‐Amino‐1,2‐diphenylethanol with Ester Enolates.
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説明
Chiral imines, derived from (1S,2R)-2-methoxy-1,2-diphenylethyl-amine and aromatic aldehydes, reacted with ester enolates prepared from ketene silyl acetals and methyllithium to give β-lactams in good yields with high diastereoselectivity. This method provides a useful and simple route for the construction of optically active β-lactam skeletons.
収録刊行物
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- Heterocycles
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Heterocycles 52 (3), 1001-1004, 1905-06-22
Japan Institute of Heterocyclic Chemistry
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詳細情報 詳細情報について
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- CRID
- 1050282676655876480
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- NII論文ID
- 120005254623
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- ISSN
- 03855414
- 15222667
- 09317597
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- HANDLE
- 10173/966
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- Web Site
- http://hdl.handle.net/10173/966
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- 本文言語コード
- en
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- 資料種別
- journal article
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- データソース種別
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- IRDB
- CiNii Articles
- OpenAIRE
