Insertion of an Oxygen Atom between Tellurium Atoms upon Oxidation of a Diaryl Telluride with NOBF4 or (CF3SO2)2O/O2: Dicationic Bis[diaryltellurium(IV)] Oxide

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NO and O2 molecules are the source of the oxygen atom for dicationic µ-oxo(diaryltellurium) dimers 2 (X=BF4- , CF3 SO3- ), which form upon chemical oxidation of 1 with NOBF4 (method A) or (CF3 SO2 )2 O/O2 [method B, Eq. (a)]. The fate of the nitrogen atom of the oxidizing agent NOBF4 remains uncertain at this stage.

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