Efficient oxygen-atom transfer agent: photochemical hydroxylation of benzene derivatives by pyrimido[5,4- ]pteridine -oxide

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Abstract Pyrimido[5,4- g ]pteridine N -oxide (1) oxidizes efficiently benzene, toluene, and anisole under UV irradiation to give the corresponding phenol derivatives 4, though the easiness of the reaction significantly depends upon the nature of the substituents on the benzene ring.

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