A novel copper(I) cluster stabilized by a dithiolate ligand having a conjugated TTF moiety

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Abstract A copper(I) complex of a dithiolate ligand which is a TTF derivative has been synthesized and characterized. The structure of this complex, [Me4N]2[Cu4(C8H6S8)3]·Me2CO, is shown to be the first example of a metal cluster coordinated with a new TTF-fused dithiolate ligand. The complex is easily oxidized and shows radical properties.

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