ChemInform Abstract: High Pressure Organic Chemistry. Part 40. Enantioselective Synthesis of Quaternary Carbon Stereogenic Centers Through the Primary Amine‐Catalyzed Michael Addition Reaction of α‐Substituted Cyclic Ketones at High Pressure.
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<jats:title>Abstract</jats:title><jats:p>Compounds bearing a quaternary carbon stereogenic center at the α‐position of cyclic ketones are obtained by an efficient new method involving the enantioselective Michael addition of cyclic ketones with acrylates using simple chiral 1‐phenylethylamine as catalyst under high pressure.</jats:p>
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- ChemInform
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ChemInform 46 2015-10-27
Wiley