ChemInform Abstract: High Pressure Organic Chemistry. Part 40. Enantioselective Synthesis of Quaternary Carbon Stereogenic Centers Through the Primary Amine‐Catalyzed Michael Addition Reaction of α‐Substituted Cyclic Ketones at High Pressure.

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<jats:title>Abstract</jats:title><jats:p>Compounds bearing a quaternary carbon stereogenic center at the α‐position of cyclic ketones are obtained by an efficient new method involving the enantioselective Michael addition of cyclic ketones with acrylates using simple chiral 1‐phenylethylamine as catalyst under high pressure.</jats:p>

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詳細情報 詳細情報について

  • CRID
    1870583642769733248
  • DOI
    10.1002/chin.201546048
  • ISSN
    15222667
    09317597
  • データソース種別
    • OpenAIRE

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