<sup>2</sup><i>J</i><sub>C,H</sub> Index: A Nondestructive NMR Method for Differentiation of Aldohexopyranosyl Residues
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説明
A new 2J(C,H) index method is described for identification of aldohexopyranose. This method is based on a fact that 2J(C,H) values reflect the stereochemistry for glycol connectivity. Based on the observed 2J(C,H) values for galactose, glucose, and mannose, 2J(C,H) profiles for other aldohexopyranoses are proposed. A combination of 2J(C,H) values was found to be useful for identification of aldohexopyranosyl residues in glycans. [structure: see text]
収録刊行物
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- Organic Letters
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Organic Letters 7 661-664, 2005-01-22
American Chemical Society (ACS)