Introduction of azetidinimine skeleton on C<sub>60</sub>

DOI DOI Research Data Open Access

Search this article

Description

<jats:title>Abstract</jats:title><jats:p>The azacyclobutane structure is introduced into C<jats:sub>60</jats:sub> fullerene using a photochemical reaction with formamidines. Three azetidinofullerenes (<jats:bold>2c–2e</jats:bold>) were synthesized; their molecular structures were characterized using <jats:sup>1</jats:sup>H, <jats:sup>13</jats:sup>C, and 2D NMR, matrix‐assisted laser desorption ionization (MALDI) mass spectrometry, visible spectroscopy, and electrochemistry. Single crystal X‐ray crystallographic analysis of <jats:bold>2e</jats:bold> reveals a unique strained four‐membered ring including nitrogen atom attached on the fullerene cage. © 2011 Wiley Periodicals, Inc. Heteroatom Chem 22:426–431, 2011; View this article online at <jats:ext-link xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="http://wileyonlinelibrary.com">wileyonlinelibrary.com</jats:ext-link>. DOI 10.1002/hc.20703</jats:p>

Journal

Related Data

See more

Details 詳細情報について

Report a problem

Back to top