Lactol-regulated silyloxy-Cope rearrangement and its application to the total synthesis of dictymal, an aldehyde possessing an iridoid dimeric structure
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説明
Dictymal, a congener of epoxydictymene isolated from a brown alga, Dictyota dichotoma has been totally synthesized via a lactol-regulated oxy-Cope rearrangement of an appropriately designed dimer obtained from two C10-synthons (iridoids).
収録刊行物
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- Journal of the Chemical Society, Perkin Transactions 1
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Journal of the Chemical Society, Perkin Transactions 1 1833-, 1989-01-01
Royal Society of Chemistry (RSC)