- 【Updated on May 12, 2025】 Integration of CiNii Dissertations and CiNii Books into CiNii Research
- Trial version of CiNii Research Knowledge Graph Search feature is available on CiNii Labs
- Suspension and deletion of data provided by Nikkei BP
- Regarding the recording of “Research Data” and “Evidence Data”
Selenium analogues of DTEDT as promising donors for organic metals
Search this article
Description
Abstract Three selenium analogues of bis-fused donor DTEDT have been synthesized. They showed four pairs of single-electron redox waves. The E 1 values are a little higher by 0.02–0.05 V than that of DTEDT (+0.37 V). On the other hand, the E 2 - E 1 values (0.12–0.13 V) are almost equal to that of DTEDT (0.13 V). TCNQ complex and cation radical salts of them show fairly high electrical conductivities (10 −1 –10 2 S-cm −1 ) and several salts show metallic conducting behavior down to 1.5–4.2 K. An X-ray crystal structure analysis of a metallic salt (DSEDS) 3 TaF 6 reveals that this salt has two-dimensional β-type packing motif of donor molecules.
Journal
-
- Synthetic Metals
-
Synthetic Metals 86 1813-1814, 1997-02-01
Elsevier BV
- Tweet
Details 詳細情報について
-
- CRID
- 1870865118044116096
-
- ISSN
- 03796779
-
- Data Source
-
- OpenAIRE