Large metal halide perovskite crystals for field-effect transistor applications

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説明

<jats:p>The material 2-phenylethylammonium tin iodide perovskite (C6H5C2H4NH3)2SnI4 [abbreviated as (PEA)2SnI4] has shown promising performance as a polycrystalline semiconductor for field-effect transistors (FETs). However, grain boundaries and structural disorder in polycrystalline films limit performance, and so the fundamental upper bounds of the material are yet to be studied. Here, we prepared large crystals of (PEA)2SnI4 for FETs and demonstrated carrier mobilities of 40 cm2 V−1 s−1 or higher, although with a low fabrication yield (&lt; 1%). Our crystal FETs were very stable when stored in air and when operated under a bias in vacuum. The FET characteristics were superior to those of reported FETs based on polycrystalline perovskite films, and these results contribute to a better understanding of basic carrier transport mechanisms in hybrid perovskite materials.</jats:p>

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詳細情報 詳細情報について

  • CRID
    1871146592451497984
  • DOI
    10.1063/1.5116411
  • ISSN
    10773118
    00036951
  • データソース種別
    • OpenAIRE

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