Photochemistry of conjugated nitrogen – carbonyl systems, 6. Photodimerization of 2,4‐dioxotetrahydropyridines

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<jats:title>Abstract</jats:title><jats:p>On irradiation in acetonitrile solution, 2,4‐dioxotetrahydropyridines <jats:bold>1</jats:bold>, the key compounds of conjugated nitrogen—carbonyl systems, undergo photodimerization to afford the <jats:italic>trans‐syn</jats:italic> dimers <jats:bold>2</jats:bold> as major products. Irradiation of <jats:italic>N</jats:italic>‐methylene‐linked bis(2,4‐dioxotetrahydropyridines) <jats:bold>3</jats:bold> led to rapid photoreaction to give <jats:bold>4</jats:bold>.</jats:p>

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