Reaction of germylene with thioketenes: Synthesis of alkylidenedigermathietanes

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<jats:title>Abstract</jats:title><jats:p>The germylenes (II), prepared by pyrolysis of the cycloadducts (I), react with di(tert‐butyl)thioketene (III) to give the digermathietanes (IV).</jats:p>

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