A Novel Two-Dimensional Non-Interpenetrating Coordination Polymer [Ag<sub>2.5</sub>L(NO<sub>3</sub>)<sub>2.5</sub>]∞ with three different coordination modes of Ag<sup>I</sup> (L = diquinoxalino[2,3-a:2′,3′-c]phenazine)

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<jats:p> A novel 2-D Ag<jats:sup>I</jats:sup> neutral infinite framework of a large delocalised system diquinoxalino[2,3-a:2′,3′-c]phenazine (L), [Ag<jats:sub>2.5</jats:sub>L(NO<jats:sub>3</jats:sub>)<jats:sub>2.5</jats:sub>]∞ (1), has been synthesised and structurally determined, in which three kinds of different coordination modes are found for the Ag<jats:sup>I</jats:sup> centers. </jats:p>

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