Spectroscopic observation of two-center three-electron bonded (hemi-bonded) structures of (H
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説明
A two-center three-electron 2c-3e bond (hemi-bond) is a non-classical chemical bond, and its existence has been supposed in radical cation clusters with lone pairs. Though the nature of the hemi-bond and its role in the reactivity of radical cations have attracted great interest, spectroscopic observations of hemi-bonded structures have been very scarce. In the present study, the presence of a stable hemi-bonded core (H
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- Chemical science
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Chemical science 8 (4), 2016-12-07
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